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91.
92.
Membrane technology is becoming more important for CO 2 separation from natural gas in the new era due to its process simplicity,relative ease of operation and control,compact,and easy to scale up as compared with conventional processes.Conventional processes such as absorption and adsorption for CO 2 separation from natural gas are generally more energy demanding and costly for both operation and maintenance.Polymeric membranes are the current commercial membranes used for CO 2 separation from natural gas.However,polymeric membranes possess drawbacks such as low permeability and selectivity,plasticization at high temperatures,as well as insufficient thermal and chemical stability.The shortcomings of commercial polymeric membranes have motivated researchers to opt for other alternatives,especially inorganic membranes due to their higher thermal stability,good chemical resistance to solvents,high mechanical strength and long lifetime.Surface modifications can be utilized in inorganic membranes to further enhance the selectivity,permeability or catalytic activities of the membrane.This paper is to provide a comprehensive review on gas separation,comparing membrane technology with other conventional methods of recovering CO 2 from natural gas,challenges of current commercial polymeric membranes and inorganic membranes for CO 2 removal and membrane surface modification for improved selectivity. 相似文献
93.
Off-Line and On-Line Preconcentration Techniques for the Determination of Phenylureas in Freshwaters
M.-C. Hennion P. Subra R. Rosset J. Lamacq P. Scribe A. Saliot 《International journal of environmental analytical chemistry》2013,93(1-4):15-33
Abstract Phenylurea herbicides are analysed by reversed-phase liquid chromatography using UV detection at 244 nm after a concentration step in order to determine ppb or sub-ppb levels in drinking and river waters. With an average UV detection limit of 5 ng, a 500 ml sample volume is necessary to reach the 10 ppt level for spiked LC grade water samples and enables easy determination of concentrations below the ppb level for river water samples. Off-line and on-line methods are compared for the concentration step. Off-line concentration consists in a liquid sorption on n-octadecyl silica (C18) and elution by a suitable organic solvent. Polar phenylureas have low retention volumes on C18 silica and consequently the length of the concentration column has to be 10 cm to concentrate them at the ppb level from 100 ml of water and longer for lower levels of detection. Nevertheless, we show that increasing the size of the concentration column does not improve the limits of detection because of the numerous interferences also concentrated when percolating high volumes of water. On-line technology can be used only with short precolumns and requires a sorbent with a great retention for phenylureas. The copolymer-based PRP-1 is found to be an excellent sorbent and it is then possible to apply on-line precolumn technology with preconcentration through two precolumns (10 × 21 mm ID) in series, the first one being packed with C18 silica and the other with the PRP-1 polymer. Interfering compounds are then trapped onto the first precolumn acting as a filter and common phenylurea-breakthrough volumes on the PRP-1 precolumn are higher than 500 ml. Knowing the amounts preconcentrated on both precolumns and using UV and electrochemical detection help the identification of phenylureas in river water. 相似文献
94.
The homogeneity of the sample load across the radial cross section of analytical scale columns was determined when operating under overload conditions. The study was performed using active flow technology columns operating in parallel segmentation mode. The outlet segmentation ratio was varied to enable different volume fractions of mobile phase, and thus sample, to elute from the peripheral and central flow regions of the column. The amount of solute exiting the peripheral and radial central exit ports was determined as a function of the flow segmentation ratio. The experimental data using an analytical scale column with dimensions, 100?×?4.6?mm, indicated that the sample load distribution was essentially uniform as a function of the column radial cross section. 相似文献
95.
现有光伏系统的控制器普遍选用微控制器为核心,为使之与电子技术课程教学案例开发相结合,提出采用集成运放替代微控制器的智能太阳能控制器方案,并以直流12V/10A小功率应用为研究实例。实验结果表明该控制器方案可行,且电路简单、成本低廉,适用于实验教学与课程设计。 相似文献
96.
《Electroanalysis》2018,30(2):345-352
We reported here three simple, low cost and easy to accomplish strategies for the fabrication of microelectrodes and other conductive patterns using ordinary office laser‐printers. In this work, toner patterns were directly printed onto the flexible substrate, acting as a mask to create the intended conductive design. To highlight the versatility of such technology, toner‐printed patterns were employed in two diverse ways: one in which the patterned toner had the exact design of the electrode and other employing a reverse toner‐printed pattern. The first one was used for the adaptation of the well‐known printed circuit board (PCB) fabrication technique, but using direct toner printing (DTP) in an already conductive flexible substrate. The second was employed for the two remaining strategies: one based on the deposition of conductive film, followed by lift‐off process; and another based on drop‐casting of a conductive ink into the formed toner cavities, followed by thermal cure. As proof‐of‐concept, all three DTP strategies were used for the fabrication of miniaturized gold electrodes in polyimide substrate, and electrochemical performance of each obtained electrode was evaluated by cyclic voltammetry. Insights about DTP technology, alignment issues, advantages, limitations and resolution of each presented approach were provided. Finally, direct toner printing showed to be a simple, affordable and quite promising technology for the fabrication of low cost point‐of‐care electrochemical devices using flexible platforms. 相似文献
97.
《Journal of separation science》2017,40(16):3343-3350
Single‐walled carbon nanohorns have received great interest for their unique properties and diverse potential applications. Herein, we demonstrated the feasibility of single‐walled carbon nanohorns incorporated poly(styrene‐divinylbenzene) monolith as the stationary phase for capillary electrochromatography, which were prepared by one‐step in situ copolymerization. Single‐walled carbon nanohorns were dispersed in styrene to give a stable and homogeneous suspension. The monolithic column gave effective separation for a wide range of aromatic compounds, which was based on hydrophobicity and π–π electrostatic stacking of single‐walled carbon nanohorns. The precisions of migration time and peak area varied in the ranges of 1.4–1.9% for intraday trials and 1.7–3.5% for interday trials, and 3.2–6.7% for intraday trials and 4.1–7.4% for interday trials, and 3.6–7.2% for inter‐column trials and 5.2–21.3% for inter‐column trials, respectively, indicating the good reproducibility of single‐walled carbon nanohorns embedded monolithic columns. 相似文献
98.
《Mendeleev Communications》2021,31(5):593-604
In this focus overview, the main types and directions of engineering, methods and techniques of intensification of chemical process systems (CPS) and process optimization of energy- and resource-efficient processes for the representative production of titanium compounds, mining waste processing systems, electrochemical coating technologies, combined technologies for the treatment of industrial effluents and energy-and resource-efficient technologies for cleaning soils from petroleum and chemical pollution products are reviewed. The following issues have been discussed: methods of complex assessment of production energy efficiency and software and information support for automated synthesis of optimal energy-efficient regenerative heat exchange systems using pinch analysis; methods and algorithms for fractal-statistical characteristics analysis of nonstationary gas flows in complex gas pipelines; methods of ecological and economic optimization of production, infrastructure supply chains; methods for assessing and preventing the dangerous environmental impact assessment of chemical pollution; organization and logistics management of business processes engineering for improving the energy efficiency of plants; engineering of problem oriented computer systems, heuristic-computational models and algorithms for intelligent integrated logistics support of the equipment life cycle; engineering developments in the field of digital transformation of energy-efficient CPS and technological production systems; application of methods for optimizing reliability factors optimization, digitalized risk and safety management in the engineering of energy- and resource efficient CPS. 相似文献
99.
K.T.A.L. Burm 《等离子体物理论文集》2013,53(3):202-205
Metal surfaces can be degreased via a combustion reaction upon the metal surface by the use of a plasma torch jet. The required energy and the reaction rate of the combustion reaction are examined here. It turns out that the reaction rate can limit the cleaning performance. In such case, the cleaning performance is not improved at higher powers. It is suggested to increase the temperature at which combustion takes place such that the cleaning performance can improve again at higher powers. (© 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
100.
Idowu David Ibrahim Tamba Jamiru Emmanuel R. Sadiku Williams Kehinde Kupolati Stephen C. Agwuncha Gbenga Ekundayo 《Composite Interfaces》2016,23(1):15-36
There has been a growing interest in the utilization of sisal fibres as reinforcement in the production of polymeric composite materials. Natural fibres have gained recognition as reinforcements in fibre polymer–matrix composites because of their mechanical properties and environmental friendliness. The mechanical properties of sisal fibre-reinforced polymer composites have been studied by many researchers and a few of them are discussed in this article. Various fibre treatments, which are carried out in order to improve adhesion, leading to improved mechanical properties, are also discussed in this review paper. This review also focuses on the influence of fibre content and fabrication methods, which can significantly affect the mechanical properties of sisal fibre-reinforced polymer composites. 相似文献